I think Matthew nailed it.
Actually, now that I think of it I think the conceptual difficulty is in the misuse of tabs here. You have a table of contents (with some details about each entry) and links to individual items. So this is in fact a hierarchy but the UI presents it as two structures that are on the same level.
So I completely agree that the single views should be available, but I do not think it should have a tab of its own, since it is the tab I can not think of a usage scenario for it. A simple return link to the listing with next/prev navigation would probably work - not unlike most blogs, actually.
In fact, now that I look at the tabs I do not think the database app has any reason to have any tabs, since none of the tabs comply to the metaphor of tabs. Add entry is a command, so it should simply have a command button with a separate page with a simple return link to the database, or maybe even a YUI dialog. Search should probably be a simple text field right on every page of the database (plus just a link to an advanced search form), like on most websites (this is a strong convention users are used to http://www.useit.com/alertbox/20040913.html and I believe this probably is not obsolete).
I would like to take a further look at this and compare similar applications. Then a blasamiq mockup + iterative usability testing. No major change in functionality, I guess - perhaps maybe a new look at the HTML templating mentioned above?
Not sure what is planned for this though, since Navigation 2.0 seems to mean tabs are going away anyway.
Assigning to Martin for his consideration. Sounds like a good feature for me (to control which tabs are available). +1